Laila Katriani, Rizky Aflaha, Ahmad Hasan As'ari, Pekik Nurwantoro, Roto Roto, Kuwat Triyana
Ammonia is toxic and can pose health risks. Ensuring the safety of individuals working with or around ammonia sensors is crucial, adding complexity to the design and use of such sensors. An ammonia gas sensor by quartz crystal microbalance coated with chitosan-overlaid polyvinyl acetate (PVAc) nanofiber has been studied to have high performance in both sensitivity and selectivity. The scanning electron microscope (SEM) and Fourier-transform infrared (FTIR) spectroscopy were used to analyze the sensing surface, which was the electrospun PVAc nanofiber with chitosan overlay. The nanofiber showed a morphological change and had a more active layer after being overlaid by chitosan. The estimation of PVAc nanofiber thickness on the QCM sensor is (12.0 ± 2.1) µm, measured using a digital microscope. The QCM sensor deposited with PVAc nanofiber only had a sensitivity of 0.076 Hz·ppm−1. It improved to 3.012 Hz·ppm−1 after overlaid with 0.7 wt% chitosan (denoted as PVAc/Ch7 sensor), an increase of 39.6 times. Moreover, the PVAc/Ch7 sensor had a rapid response and recovery times of 9 and 35 s with a very low detection limit of 0.526 ppm. The sensor also exhibited good selectivity toward other analytes. In addition, the sensor also had outstanding in other performances, such as linearity, repeatability, reversibility, and excellent long-term stability. This proposed QCM-based ammonia sensor could be an alternative to analyzing ammonia in various fields. © 2024 Elsevier B.V.
Department of Physics, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, BLS 21, Yogyakarta, 55281, Indonesia; Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, BLS 21, Yogyakarta, 55281, Indonesia; Department of Physics Education, Faculty of Mathematics and Natural Sciences, Universitas Negeri Yogyakarta, Karangmalang, Yogyakarta, 55281, Indonesia; Research Center for Advanced Materials, National Research and Innovation Agency, Building 440-442 Kawasan Puspiptek Serpong, Tangerang Selatan, 15314, Indonesia
